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61.
Rivers and streams are unstable environments in which estimation of energetic costs and benefits of habitat utilization are the daunting exercise. Empirical models of food consumption may be used to estimate energetic benefits based on abiotic and biotic conditions in patches of habitat. We performed thirty daily surveys of fish stomach contents to estimate the consumption rates for juvenile Atlantic salmon (Salmo salar) in a river. The data were used to assess whether variations of daily consumption rates existed within the river, and to develop empirical models that could predict fish consumption rates using abiotic and biotic conditions as independent variables. Daily consumption rates based on stomach content surveys in the field (range: 0.15–1.49 g dry/(100 g wet day)) varied significantly depending on habitat patch (500–1000 m2), summer period, and sampling year. Variables such as water temperature, numerical density of salmon, water depth and moon phase explained 83–93% of the variations in daily food consumption rates. Daily consumption rates tended to increase with water temperature and depth, and were also higher near a full moon. However, they tended to decrease with the numerical density of salmon. Our work suggests that empirical models based on independent variables that are relatively simple to estimate in the field may be developed to predict fish consumption rates in different habitat patches in a river.  相似文献   
62.
Thin layers of plankton have been documented in a wide variety of environments. The growing body of observations indicates that these features are a critical component of marine ecosystem dynamics and functioning. In the past two decades, much of the research on thin layers was undertaken in temperate coastal waters. Here, we report the first known observations of thin layers of phytoplankton in tropical Hawaiian waters. We conducted an overnight shipboard study during which time we made high-resolution observations of physical and optical structure in the water column. During the overnight cruise, we observed the greatest number of thin layers in the early evening hours when thermal stratification was strongest and most persistent due to a combination of warm air and surface water, as well as light winds. A comparison of these observations with those from temperate regions leads us to hypothesize that the nature and persistence of the physical structure is very important in determining the persistence of thin layered structures. Because plankton biomass is generally lower in tropical regions, the heterogeneous aggregation of food in thin subsurface layers may be more critical to the marine ecosystem than it is in temperate regions where plankton are generally more abundant.  相似文献   
63.
The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.  相似文献   
64.
The 20 ka ~0.1 km3 Omega dacite, which erupted shortly after the 26.5 ka Oruanui super-eruption, compositionally stands out among Taupo Volcanic Zone (TVZ) magmas, which are overwhelmingly characterized by rhyolites (>90 % by volume). The previously reported presence of inherited zircons in this zircon-undersaturated magma has provided unequivocal evidence for the involvement of upper-crustal material in a 1–10 year timescale prior to the Omega eruption. However, whether this crustal involvement is characterized by wholesale, melting of preexisting crust or subordinate bulk assimilation into an already differentiated magma body remains unclear. To disentangle these processes, we describe the mineral chemistry of the major phases present in the Omega dacite and determine intensive parameters describing magma chamber conditions. Dominantly unimodal populations of plagioclase (An50–60), orthopyroxene (Mg# from 58 to 68), and clinopyroxene (Mg# from 65 to 73), along with coexisting equilibrium pairs of Fe–Ti oxides, constrain pre-eruptive temperatures to 850–950 °C, a pressure between ~3 and 7 kbars, and an oxygen fugacity of ~NNO. MELTS thermodynamic modeling suggests that this phase assemblage is in equilibrium with the bulk rock and glass compositions of the Omega dacite at these estimated PTfO2 pre-eruptive conditions. Combining these petrological observations with insights into conductive thermal models of magma–crust interactions, we argue that the Omega dacite more likely formed in the mid-to-lower crust via protracted processing through fractional crystallization coupled with some assimilation (AFC). Incorporation of crustal material is likely to have occurred at various stages, with the inherited zircons (and potentially parts of glomerocrysts) representing late and subordinate upper-crustal assimilants. This petrogenetic model is consistent with the presence of a differentiating crustal column, consisting of a polybaric fractional crystallization and assimilation history. On the basis of petrological, thermal, and geophysical considerations, upper-crustal reservoirs, which feed large-scale rhyolitic volcanism in the TVZ, most likely take the form of large, long-lived crystal mush zones. Following large eruptions, such as the Oruanui event, this mush is expected to crystallize significantly (up to 70–80 vol% crystals) due to syn-eruptive decompression. Hence, the Omega dacite, immediately post-dating the Oruanui event, potentially represents incoming deeper recharge of less-evolved magma that was able to penetrate the nearly solidified upper-crustal mush. Over the past 20,000 years, similar intermediate recharge magmas have incrementally reheated, reconstructed, and reactivated the upper-crustal mush zone, allowing a gradual return to rhyolitic volcanism at the Taupo Volcanic Center.  相似文献   
65.
66.
Contaminated groundwater in fractured bedrock can expose ecosystems to undesired levels of risk for extended periods due to prolonged back-diffusion from rock matrix to permeable fractures. Therefore, it is key to characterize the diffusive mass loading (intrusion) of contaminants into the rock matrix for successful management of contaminated bedrock sites. Even the most detailed site characterization techniques often fail to delineate contamination in rock matrix. This study presents a set of analytical solutions to estimate diffusive mass intrusion into matrix blocks, it is recovered by pumping and concentration rebound when pumping ceases. The analytical models were validated by comparing the results with (1) numerical model results using the same model parameters and (2) observed chloride mass recovery, rebound concentration, and concentration in pumped groundwater at a highly fractured bedrock site in Alberta, Canada. It is also demonstrated that the analytical solutions can be used to estimate the total mass stored in the fractured bedrock prior to any remediation thereby providing insights into site contamination history. The predictive results of the analytical models clearly show that successful remediation by pumping depends largely on diffusive intrusion period. The results of initial mass from the analytical model was used to successfully calibrate a three-dimensional discrete fracture network numerical model further highlighting the utility of the simple analytical solutions in supplementing the more detailed site numerical modeling. Overall, the study shows the utility of simple analytical methods to support long-term management of a contaminated fractured bedrock site including site investigations and complex numerical modeling.  相似文献   
67.
The general philosophy of seismic hazard evaluation described here is appropriate for selection of seismic input to regional earthquake engineering codes prior to detailed on-site inspections and geotechnical assessments. Some probabilistic seismic hazard methodologies which can be applied in areas of low and high seismicity, are briefly described to emphasise the main equations with specimen results. Three aspects of hazard assessment are explored by different pathways. These include the analysis of regional earthquake catalogues to obtain magnitude recurrence, particularly using Gumbel extreme value statistics. This is extended to assess ground shaking hazard which is usually sought by earthquake engineers. Thirdly, the concept of earthquake perceptibility is developed, leading to the identification of an earthquake magnitude or type which is characteristic of a region. This most perceptible earthquake is most likely to be felt at any site in a region and provides an earthquake selection criterion which can be used in aseismic design of noncritical structures. Because there are several methods of seismic hazard evaluation, the view is expressed that it is sensible for practical purposes to seek results from different methods or different pathways to the hazard evaluation.Paper presented at the Commission of the European Communities' School on Earthquake Hazard Evaluation, Athens, and at the 21st General Assembly of the European Seismological Commission, held in Sofia, 1988.Now at School of Environmental Sciences, University of East Anglia, University Plain, Norwich NR4 7TJ, U.K.  相似文献   
68.
Schwertmannite (Fe8O8(OH)6SO4) is a common Fe(III)-oxyhydroxysulfate mineral in acid-sulfate systems, where its formation and fate strongly influence water quality. The present study examines transformation of schwertmannite to goethite (FeOOH), as catalyzed by interactions with Fe(II) in anoxic aquatic environments. This study also evaluates the role of the Fe(II) pathway in influencing the formation of iron-sulfide minerals in such environments. At pH > 5, the rates of Fe(II)-catalyzed schwertmannite transformation were several orders of magnitude faster than transformation in the absence of Fe(II). Complete transformation of schwertmannite occurred within only 3-5 h at pH > 6 and Fe(II)(aq) ? 5 mmol L−1. Model calculations indicate that the Fe(II)-catalyzed transformation of schwertmannite to goethite greatly decreases the reactivity of the Fe(III) pool, thereby favoring SO4-reduction and facilitating the formation of iron-sulfide minerals (particularly mackinawite, tetragonal FeS). Examination of in situ sediment geochemistry in an acid-sulfate system revealed that the rapid Fe(II)-catalyzed transformation was consistent with an abrupt shift from an acidic Fe(III)-reducing regime with abundant schwertmannite near the sediment surface, to a near-neutral mackinawite-forming regime where goethite was dominant. This study demonstrates that the Fe(II) pathway exerts a major influence on schwertmannite transformation and iron-sulfide formation in anoxic acid-sulfate systems. These findings have important implications for understanding acidity dynamics and trace element mobility in such systems.  相似文献   
69.
We present evidence for Ly pumping of the Lyman band system of molecular hydrogen in Herbig-Haro 7 and the bipolar outflow DR 21. For this study we have measured several vibrational-rotational emission lines of H2 whose energy levels are widely spaced and ranging from 6000 (v = 1) to 25000 Kelvin (v = 4). We show that the near-infrared H2 emission from the shocked gas in HH 7 can be well described by a bow C-type shock. The enhanced emission observed from the higher energy levels (v > 3) can be well modelled by employing the Ly pumping mechanism.In the DR 21 outflow the multi-line study showed that different physical conditions exist in the eastern and western emission lobes. The higher H2 line ratios measured in the eastern lobe suggests a higher Ly pump rate which may be locally produced in the fast bowshocks. The FUV radiation field emanating from the central HII regions may in addition be exciting the Lyman and Werner bands of H2 in the molecular lobes.We show that the observed H2 emission can be interpreted in terms of a simple model consisting of a C-type bowshock, which produces the low excitation H2 emission, and a FUV radiation field with enough Ly line radiation to produce the high excitation H2 emission through fluorescence.  相似文献   
70.
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